Iron isotope variations in spinel peridotite xenoliths from North China Craton: implications for mantle metasomatism   总被引：2，自引：1，他引：1  

Xinmiao Zhao  Hongfu Zhang  Xiangkun Zhu  Suohan Tang  Yanjie Tang 《Contributions to Mineralogy and Petrology》2010,160(1):1-14

Iron isotopes, together with mineral elemental compositions of spinel peridotite xenoliths and clinopyroxenites from Hannuoba and Hebi Cenozoic alkaline basalts, were analyzed to investigate iron isotopic features of the lithospheric mantle beneath the North China Craton. The results show that the Hannuoba spinel peridotite xenoliths have small but distinguishable Fe isotopic variations. Overall variations in δ⁵⁷Fe are in a range of ?0.25 to 0.14‰ for olivine, ?0.17 to 0.17‰ for orthopyroxene, ?0.21 to 0.27‰ for clinopyroxene, and ?0.16 to 0.26‰ for spinel, respectively. Clinopyroxene has the heaviest iron isotopic ratio and olivine the lightest within individual sample. No clear linear relationships between the mineral pairs on “δ-δ” plot suggest that iron isotopes of mineral separates analyzed have been affected largely by some open system processes. The broadly negative correlations between mineral iron isotopes and metasomatic indexes such as spinel Cr#, (La/Yb)_N ratios of clinopyroxenes suggest that iron isotopic variations in different minerals and peridotites were probably produced by mantle metasomatism. The Hebi phlogopite-bearing lherzolite, which is significantly modified by metasomatic events, appears to be much heavier isotopically than clinopyroxene-poor lherzolite. This study further confirms previous conclusions that the lithospheric mantle has distinguishable and heterogeneous iron isotopic variations at the xenoliths scale. Mantle metasomatism is the most likely cause for the iron isotope variations in mantle peridotites.  相似文献   

广西新元古代BIF的铁同位素特征及其地质意义   总被引：10，自引：1，他引：9  

闫斌  朱祥坤  唐索寒  朱茂炎  朱祥坤 《地质学报》2010,84(7):1080-1086

通过分析广西三江地区新元古代条带状含铁建造的Fe同位素和主量元素组成,对海水的氧化还原状态提供了制约,为富禄期的地球处于间冰期提供了证据。相对于标准物质IRMM-014,新元古代含铁建造不同条带全岩样品的δ57Fe值变化范围1.60‰～2.20‰,平均值为1.85‰,表明BIF样品富集铁的重同位素。条带状含铁建造主要由Fe2O3和SiO2组成,但却具有较高的Al2O3含量。这表明条带状含铁建造样品不是纯净的化学沉积物,而是具有一定的碎屑物质输入。碎屑输入量的不同引起深色和浅色条带之间铁同位素组成存在着0.4‰的差别。剔除碎屑的影响,新元古代BIF从海水中沉淀的赤铁矿δ57Fe的平均值在2‰左右,略高于太古代条带状铁建造的Fe同位素组成,这表明当时海水的氧逸度可能比太古代还低。这说明在富禄期绝大部分海洋仍旧被冰盖覆盖,只在局部出现融化。因此,富禄期的地球可能出于冰期的相对温暖阶段,而不是间冰期。  相似文献   

河南嵩县南岭超贫磁铁矿的地质特征与找矿模式   总被引：2，自引：0，他引：2  

周红春  刘传权  李中明  王柳林  孙丹  崔川生 《现代地质》2010,24(1)

随着国民经济的快速发展,传统的铁矿资源越来越紧缺,迫切需要寻找和开发非传统的铁矿资源。河南嵩县南岭超贫磁铁矿(mFe,其含量为10.20%)品位低,易采易选,性质上可归属于非传统矿产资源。通过对南岭超贫磁铁矿的磁铁矿石、斜长角闪(片)岩化学成分的对比分析,结合矿区地质特征和矿体特征,对矿体进行n(Fe+Al+Ti)-n(Ca+Mg)和w(FeO+Fe2O3+TiO2)-w(Al2O3)-w(MgO)图解分析,结果显示南岭矿区的含磁铁斜长角闪(片)岩和斜长角闪(片)岩是大洋富铁拉斑玄武岩经变质作用而形成的,矿床的成因类型为风化残积型超贫铁矿床。进一步厘定了找矿标志,建立了找矿模式,对寻找南岭型铁矿有一定的借鉴意义。  相似文献   

Concentrations and contamination trends of heavy metals in the sediment cores of Taihu Lake,East China,and their relationship with historical eutrophication   总被引：2，自引：0，他引：2  

Zhangdong Jin  Hangxin Cheng  Li Chen  Xiangdong Li  Guangwei Zhu  Guangmin Zhuang  Na Qian 《中国地球化学学报》2010,29(1):33-41

To assess the contamination trends and potential bio-availability of sediment-bound heavy metals, concentrations of heavy metals in acid-leaching fraction and in bulk sediments from the two typical bays (the Meiliang Bay and Xuhu Bay) of the Taihu Lake, East China, were studied. Pb and Zn showed elevated concentrations in the sediments from both areas, although sedimentation history and degree of pollution are different between the two bays. In the Meiliang Bay, both Pb and Zn pollutions started in the late 1970’s, the same time as the beginning of eutrophication of the lake, while the in the Xuhu Bay the metal contamination started since recent 10 years. The concentrations of acid-leachable Pb in the sediments from the Meiliang Bay are correlated with the historical eutrophication process. Before the eutrophication and heavy metal pollution, the chemical properties of the lake sediments were the same as the source compositions of the Xiashu loess. Both Pb and Zn in the sediments mainly occur in leachable forms by nitric or hydrochloric acid, whilst most of Cu is in residual fraction. The results indicate that both Pb and Zn may have higher mobility and bioavailability in water and biology than Cu.  相似文献   

俄罗斯水热法合成祖母绿的宝石学特征研究     

孙主  李娅莉 《地质科学译丛》2010,(1):12-15,42,I0002

俄罗斯水热法合成祖母绿是珠宝界较关注的产品。选用5粒俄罗斯水热法合成祖母绿样品进行了常规宝石学特征测试、电子探针成分分析、红外吸收光谱和紫外-可见吸收光谱测定。结果表明,俄罗斯水热法合成祖母绿样品以低碱、富Fe与Cr为特征,折射率和相对密度明显偏高,红外吸收光谱特征峰出现在4052cm叫附近;俄罗斯水热法合成祖母绿样品的致色元素为Cr与Fe。同时,对比分析了俄罗斯、桂林水热法合成祖母绿样品和天然祖母绿样品的宝石学特征。  相似文献   

邻二氮杂菲银/蒙脱石复合物的XPS和TG研究     

杨丹  袁鹏  朱建喜  何宏平 《矿物岩石》2010,30(2)

用微波辐射法制备了邻二氮杂菲银/蒙脱石抗菌复合物。以X射线光电子能谱(XPS)及热重分析(TG/DTG)对抗菌复合物及其热处理产物的表面特性及热稳定性进行探讨。结果表明:邻二氮杂菲银络离子插入到蒙脱石层间后,层间水含量减少。样品表面的银以邻二氮杂菲银络合物的状态存在,煅烧温度低于或等于200℃时,邻二氮杂菲银络合物没有发生分解;当煅烧温度到达300℃时,邻二氮杂菲银络合物开始分解产生新的物质Ag2O;当煅烧温度到达400℃时,样品表面开始有银粒子产生,随着温度的增加,银粒子的粒径不断增加。  相似文献   

河南省地热资源开发利用现状评价   总被引：2，自引：0，他引：2  

王心义  黄丹 《地下水》2010,32(1):54-55,70

基于河南省地热资源特点及其开发利用现状的基础上,分析总结了河南省各种类型地热水的开采情况。首先应用已采量与可采量的比值作为评价标准将地热水的开发利用程度为五类,评价了整个河南省新生界地热水、基岩地热水、温泉水的开发利用情况以及各地市城区的地热开采情况,提出河南省应积极地推广地热资源利用,对开采过热的地区要注意防止地热水位下降过快,对开采一般的地区要注意适度开发,对其他地区要结合自身实际鼓励开发。  相似文献   

长江三峡库区全新世环境考古研究进展          下载免费PDF全文

朱诚  马春梅  李兰  孙智彬  郑朝贵  白九江  朱光耀  黄润 《地学前缘》2010,17(3):222

充分利用长江三峡工程文物抢救性发掘的宝贵机会,通过对重庆市忠县中坝遗址、丰都县玉溪遗址等典型遗址和神农架大九湖泥炭地层环境考古研究,摸索出了一套利用年代学、沉积学、重矿物组分鉴定、锆石形态统计、地球化学和环境磁学方法辨别考古遗址地层中古洪水沉积的方法;建立了该区地表孢粉-气候的转换函数,并将其用于对神农架大九湖泥炭地层的研究,弄清了该区全新世以来环境演变的背景,并将自然沉积地层环境演变记录与典型考古遗址地层古洪水事件作了对比分析。遗址时空分布研究表明:长江三峡库区旧石器时代至宋代677处遗址时空分布总趋势是从西往东、从高往低逐渐增加的,遗址多沿江河分布,且在河流交汇处呈聚集状态,这与人类多选择河流1～2级阶地为生、河流交汇处鱼类资源丰富有关。研究表明:中坝遗址能延续5000a的原因一方面与其盐业遗址的属性有关,另一方面与其长期具有良好生态环境有关。从该遗址T0202探方出土近20万件动物骨骼的分类统计证明了这一点。7.6kaBP以来,水位在吴淞高程147.024m以上的古洪水至少在玉溪遗址T0403探方中留下了16次沉积记录。神农架大九湖297cm厚的泥炭及其148个孢粉样品和10个AMS14C测年数据表明,该泥炭地层为本项目提供了理想的全新世自然环境演变背景,尤其8.2kaBP前后的降温事件很明显,6.7～4.2kaBP为中全新世最适宜期,4.2kaBP前后由暖湿转为凉干,3.5～0.9kaBP季风降水整体较弱,0.9kaBP前后转为较凉湿。根据对中坝和玉溪两处遗址地层的研究,在8.2～6.7kaBP期间出现有10个古洪水层;在6.7～4.2kaBP全新世最适宜期遗址地层中出现有8个古洪水层;在3.5～0.9kaBP降水减少的时期,中坝遗址中仅出现2个洪水层(即西周时期的37-1和战国早期的第21层);在0.9kaBP以来降水较多的时期,中坝遗址中存在3个洪水层(即宋代中期的11C-1层、清代的5-1层和1981年的2B-2层)。这表明,8.2～6.7kaBP的洪水在三峡地区次数是最多的,6.7～4.2kaBP的洪水数量次之。长江三峡库区的这一古洪水发生规律或许可以解释长江中游的江汉平原在7.8～5.1kaBP期间遗址数量偏少的原因。  相似文献   

低氧低分压环境下泡塑吸附-石墨炉原子吸收光谱法测定化探样品中的痕量金   总被引：2，自引：1，他引：1  

王祝  邵蓓  邬国栋  李明礼 《岩矿测试》2010,29(3):282-286

针对西藏低氧低分压环境下痕量金的测定,探讨了溶矿介质、解脱时间、吸附温度、Fe3+加入量等对测定结果的影响。确定了最佳测定条件,并较详细讨论了Fe3+在溶矿和吸附过程中的重要作用。方法检出限为0.102 ng/g,测定范围为0.24~300 ng/g,准确度(ΔlgC,n=12)为0.01~0.03,精密度(RSD,n=12)为1.61%~7.33%,很好地解决了西藏地区低氧低分压低温环境下痕量金测定的技术难题。  相似文献   

Native antimony in the Baogutu gold deposit (west Junggar,NW China): Its occurrence and origin     

Fang An  Yongfeng Zhu 《Ore Geology Reviews》2010,37(3-4):214-223

The Baogutu gold deposit, West Junggar (Xinjiang, NW China), is composed of quartz–sulfide veins and their stockworks and is hosted within an Early Carboniferous volcanic–sedimentary sequence. Three ore-forming paragenetic stages can be identified: coarse-grained quartz–sulfide vein (stage I), gold-bearing fine-grained quartz–sulfide vein (stage II), and native antimony-bearing calcite–sulfide veinlets (stage III). The estimated formation temperatures (approximately 360 to 220 °C), fS₂ (? 7 to ? 15 log units), and fO₂ (? 26 to ? 43 log units) decrease from stage I, through stage II, to stage III. The nature of the hydrothermal fluid changed from weakly acidic (pH: 5 to 6 at stage I) to alkaline (pH: > 7 at stage III).Two different occurrences of native antimony could be identified: one coexists with chalcopyrite and pyrrhotite, whereas the other occurs as isolate grains within calcite veins. Native antimony (up to 100 μm in size) contains minor amounts of As (2.0 to 2.7 wt.%); empirical formula Sb_0.95–0.96As_0.03–0.04. Decrease of temperature and fO₂ at high pH and low fS₂ conditions favored co-precipitation of native antimony–ullmannite assemblages and the decomposition of tetrahedrite. Native antimony crystallized later than the native gold, suggesting fractionation between Au and Sb during the hydrothermal evolution of the deposit.  相似文献